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1 article(s) from Afsina, Cheriya Mukkolakkal Abdulla

Recent advances and perspectives in ruthenium-catalyzed cyanation reactions

Thaipparambil Aneeja,
Cheriya Mukkolakkal Abdulla Afsina,
Padinjare Veetil Saranya and
Gopinathan Anilkumar

Beilstein J. Org. Chem. 2022, 18, 37–52, doi:10.3762/bjoc.18.4

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Graphical Abstract

Scheme 1: Starch-immobilized ruthenium trichloride-catalyzed cyanation of tertiary amines.

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Scheme 2: Proposed mechanism for the cyanation of tertiary amines using starch-immobilized ruthenium trichlor...

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Scheme 3: Cyanation of tertiary amines using heterogeneous Ru/C catalyst.

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Scheme 4: Proposed mechanism for cyanation of tertiary amines using a heterogeneous Ru/C catalyst.

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Scheme 5: Ruthenium-carbamato complex-catalyzed oxidative cyanation of tertiary amines.

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Scheme 6: Cyanation of tertiary amines using immobilized MCM-41-2N-RuCl₃ as the catalyst.

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Scheme 7: Cyanation of tertiary amines using RuCl₃·nH₂O as the catalyst and molecular oxygen as oxidant.

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Scheme 8: RuCl₃-catalyzed cyanation of tertiary amines using NaCN/HCN and H₂O₂ as oxidant.

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Scheme 9: Proposed mechanism for the ruthenium-catalyzed oxidative cyanation using H₂O₂.

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Scheme 10: Proposed mechanism for the ruthenium-catalyzed aerobic oxidative cyanation.

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Scheme 11: RuCl₃-catalyzed oxidative cyanation of tertiary amines using acetone cyanohydrin as the cyanating a...

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Scheme 12: Cyanation of indoles using K₄[Fe(CN)₆] as cyano source and Ru(III)-exchanged NaY zeolite (RuY) as c...

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Scheme 13: Cyanation of arenes and heteroarenes using a ruthenium(II) catalyst and N-cyano-N-phenyl-p-toluenes...

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Scheme 14: Proposed mechanism for the cyanation of arenes and heteroarenes using ruthenium(II) as catalyst and...

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Scheme 15: Synthesis of N-(2-cyanoaryl)-7-azaindoles.

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Figure 1: Structure of the TiO₂-immobilized ruthenium polyazine complex.

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Scheme 16: Visible-light-induced oxidative cyanation of aza-Baylis–Hillman adducts.

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Scheme 17: Synthesis of 1° alkyl nitriles using [Ru(bpy)₃](PF₆)₂ as the photocatalyst.

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Scheme 18: Synthesis of 2° and 3° alkyl nitriles using [Ru(bpy)₃](PF₆)₂ as the photocatalyst.

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Scheme 19: Photoredox cross coupling reaction.

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Scheme 20: Synthesis of α-amino nitriles from amines via a one-pot strategy.

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Scheme 21: Proposed mechanistic pathway for the cyanation of the aldimine intermediate.

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Scheme 22: Strecker-type functionalization of N-aryl-substituted tetrahydroisoquinolines under flow conditions....

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Scheme 23: One-pot synthesis of α-aminonitriles using RuCl₃ as catalyst.

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Scheme 24: Synthesis of alkyl nitriles using (Ru(TMHD)₃) as the catalyst.

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Scheme 25: Synthesis of cyanated isoxazolines from alkenyl oximes catalyzed by [RuCl₂(p-cymene)]₂ in the prese...

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Scheme 26: Proposed mechanism for the synthesis of cyanated isoxazolines from alkenyl oximes.

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Scheme 27: Oxidative cyanation of differently substituted alcohols.

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Review

Published 04 Jan 2022

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